Book/Report FZJ-2018-00402

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Pyrolysis of methane by microwaves Part II Sampling the Plasma by Time of flight Mass Spectrometry Part III Kinetics of lon-Molecule Reactions

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1975
Kernforschungsanlage Jülich, Verlag Jülich

Jülich : Kernforschungsanlage Jülich, Verlag, Berichte der Kernforschungsanlage Jülich 1188,02-03 33,16 p. ()

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Report No.: Juel-1188-02-03

Abstract: $\underline{Part II}$ The methane microwave plasma was sampled by a time of flight mass spectrometer through a nozzle of about 20$\mu$m diameter. The massspectra of the various gaseous species in the microwave plasma shows a polymerization process of higher hydrocarbons up to C$_{12}$. Reactions of various types such as ion molecule and excited radical molecules leading to the polymer formation are discussed. $\underline{Part III}$ The kinetics of the chemical reactions in the polymerization process of methane in a microwave plasma was investigated. Reaction rates, together with their enthalpies were calculated and discussed. Two different " path ways" for the polymerization process are given and discussed.


Contributing Institute(s):
  1. Publikationen vor 2000 (PRE-2000 ; Retrocat)
Research Program(s):
  1. 899 - ohne Topic (POF3-899) (POF3-899)

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 Record created 2018-01-12, last modified 2021-01-29